Efficient palladium-catalyzed coupling of aryl chlorides and tosylates with terminal alkynes: use of a copper cocatalyst inhibits the reaction D Gelman, SL Buchwald Angewandte Chemie International Edition 42 (48), 5993-5996, 2003 | 490 | 2003 |
Copper-catalyzed C− P bond construction via direct coupling of secondary phosphines and phosphites with aryl and vinyl halides D Gelman, L Jiang, SL Buchwald Organic Letters 5 (13), 2315-2318, 2003 | 377 | 2003 |
Ligand–metal cooperation in PCP pincer complexes: rational design and catalytic activity in acceptorless dehydrogenation of alcohols S Musa, I Shaposhnikov, S Cohen, D Gelman Angewandte Chemie International Edition 50 (15), 3533-3537, 2011 | 261 | 2011 |
Formic acid, a biomass-derived source of energy and hydrogen for biomass upgrading F Valentini, V Kozell, C Petrucci, A Marrocchi, Y Gu, D Gelman, L Vaccaro Energy & Environmental Science 12 (9), 2646-2664, 2019 | 217 | 2019 |
Novel trans-spanned palladium complexes as efficient catalysts in mild and amine-free cyanation of aryl bromides under air O Grossman, D Gelman Organic Letters 8 (6), 1189-1191, 2006 | 200 | 2006 |
meta‐C−H Bromination on Purine Bases by Heterogeneous Ruthenium Catalysis S Warratz, DJ Burns, C Zhu, K Korvorapun, T Rogge, J Scholz, C Jooss, ... Angewandte Chemie International Edition 56 (6), 1557-1560, 2017 | 141 | 2017 |
Coordination Versatility of sp3-Hybridized Pincer Ligands toward Ligand–Metal Cooperative Catalysis D Gelman, S Musa ACS Catalysis 2 (12), 2456-2466, 2012 | 132 | 2012 |
γ-Valerolactone as a renewable dipolar aprotic solvent deriving from biomass degradation for the Hiyama reaction E Ismalaj, G Strappaveccia, E Ballerini, F Elisei, O Piermatti, D Gelman, ... ACS Sustainable Chemistry & Engineering 2 (10), 2461-2464, 2014 | 128 | 2014 |
Palladium-catalyzed methylation of aryl and vinyl halides by stabilized methylaluminum and methylgallium complexes J Blum, D Gelman, W Baidossi, E Shakh, A Rosenfeld, Z Aizenshtat, ... The Journal of Organic Chemistry 62 (25), 8681-8686, 1997 | 101 | 1997 |
Dehydrogenative Cross‐Coupling of Primary and Secondary Alcohols S Musa, L Ackermann, D Gelman Advanced Synthesis & Catalysis 355 (14‐15), 3077-3080, 2013 | 95 | 2013 |
Cobalt (III)-catalyzed allylation with allyl acetates by C–H/C–O cleavage M Moselage, N Sauermann, J Koeller, W Liu, D Gelman, L Ackermann Synlett 26 (11), 1596-1600, 2015 | 94 | 2015 |
New Shapes of PC(sp3)P Pincer Complexes C Azerraf, D Gelman Organometallics 28 (22), 6578-6584, 2009 | 93 | 2009 |
Single‐Component Phosphinous Acid Ruthenium (II) Catalysts for Versatile C− H Activation by Metal–Ligand Cooperation D Zell, S Warratz, D Gelman, SJ Garden, L Ackermann Chemistry–A European Journal 22 (4), 1248-1252, 2016 | 90 | 2016 |
Bifunctional ruthenium (II) PCP pincer complexes and their catalytic activity in acceptorless dehydrogenative reactions S Musa, S Fronton, L Vaccaro, D Gelman Organometallics 32 (10), 3069-3073, 2013 | 90 | 2013 |
Palladium complexes bearing novel strongly bent trans-spanning diphosphine ligands: Synthesis, characterization, and catalytic activity O Grossman, C Azerraf, D Gelman Organometallics 25 (2), 375-381, 2006 | 80 | 2006 |
Exploring the Reactivity of C(sp3)‐Cyclometalated IrIII Compounds in Hydrogen Transfer Reactions C Azerraf, D Gelman Chemistry–A European Journal 14 (33), 10364-10368, 2008 | 76 | 2008 |
Dichlorobis (triphenylphosphine) nickel-catalyzed cross-coupling of aryl chlorides with intramolecularly stabilized group 13 metal alkylating reagents D Gelman, H Schumann, J Blum Tetrahedron Letters 41 (39), 7555-7558, 2000 | 64 | 2000 |
Efficient E‐Selective Transfer Semihydrogenation of Alkynes by Means of Ligand‐Metal Cooperating Ruthenium Catalyst S Musa, A Ghosh, L Vaccaro, L Ackermann, D Gelman Advanced Synthesis & Catalysis 357 (10), 2351-2357, 2015 | 63 | 2015 |
Trans-chelating ligands in palladium-catalyzed carbonylative coupling and methoxycarbonylation of aryl halides L Kaganovsky, D Gelman, K Rueck-Braun Journal of Organometallic Chemistry 695 (2), 260-266, 2010 | 60 | 2010 |
Palladium-catalyzed cross-alkynylation of aryl bromides by sodium tetraalkynylaluminates D Gelman, D Tsvelikhovsky, GA Molander, J Blum The Journal of Organic Chemistry 67 (18), 6287-6290, 2002 | 60 | 2002 |