Role (s) of TMA in polymerization C Ehm, R Cipullo, PHM Budzelaar, V Busico Dalton Transactions 45 (16), 6847-6855, 2016 | 71 | 2016 |
Catalyst activation and the dimerization energy of alkylaluminium compounds C Ehm, G Antinucci, PHM Budzelaar, V Busico Journal of Organometallic Chemistry 772, 161-171, 2014 | 61 | 2014 |
Calculating accurate barriers for olefin insertion and related reactions C Ehm, PHM Budzelaar, V Busico Journal of Organometallic Chemistry 775, 39-49, 2015 | 57 | 2015 |
Accurate prediction of copolymerization statistics in molecular olefin polymerization catalysis: The role of entropic, electronic, and steric effects in catalyst comonomer affinity F Zaccaria, C Ehm, PHM Budzelaar, V Busico ACS Catalysis 7 (2), 1512-1519, 2017 | 56 | 2017 |
Selective copper complex-catalyzed hydrodefluorination of fluoroalkenes and allyl fluorides: a tale of two mechanisms NO Andrella, N Xu, BM Gabidullin, C Ehm, RT Baker Journal of the American Chemical Society 141 (29), 11506-11521, 2019 | 50 | 2019 |
Cyclic polyacetylene Z Miao, SA Gonsales, C Ehm, F Mentink-Vigier, CR Bowers, BS Sumerlin, ... Nature chemistry 13 (8), 792-799, 2021 | 48 | 2021 |
Backbone rearrangement during olefin capture as the rate limiting step in molecular olefin polymerization catalysis and its effect on comonomer affinity F Zaccaria, R Cipullo, PHM Budzelaar, V Busico, C Ehm Journal of Polymer Science Part A: Polymer Chemistry 55 (17), 2807-2814, 2017 | 42 | 2017 |
Connection of Stereoselectivity, Regioselectivity, and Molecular Weight Capability in rac-R′2Si(2-Me-4-R-indenyl)2ZrCl2 Type Catalysts C Ehm, A Vittoria, GP Goryunov, PS Kulyabin, PHM Budzelaar, ... Macromolecules 51 (20), 8073-8083, 2018 | 36 | 2018 |
MgCl2-Supported Ziegler–Natta Catalysts: a DFT-D “Flexible-Cluster” Approach to Internal Donor Adducts E Breuza, G Antinucci, PHM Budzelaar, V Busico, A Correa, C Ehm The Journal of Physical Chemistry C 122 (16), 9046-9053, 2018 | 33 | 2018 |
Reactivity trends of lewis acidic sites in methylaluminoxane and some of its modifications F Zaccaria, PHM Budzelaar, R Cipullo, C Zuccaccia, A Macchioni, ... Inorganic Chemistry 59 (8), 5751-5759, 2020 | 31 | 2020 |
ansa-Zirconocene Catalysts for Isotactic-Selective Propene Polymerization at High Temperature: A Long Story Finds a Happy Ending PS Kulyabin, GP Goryunov, MI Sharikov, VV Izmer, A Vittoria, ... Journal of the American Chemical Society 143 (20), 7641-7647, 2021 | 30 | 2021 |
An Integrated High Throughput Experimentation/Predictive QSAR Modeling Approach to ansa-Zirconocene Catalysts for Isotactic Polypropylene C Ehm, A Vittoria, GP Goryunov, VV Izmer, DS Kononovich, ... Polymers 12 (5), 1005, 2020 | 29 | 2020 |
High-throughput experimentation in olefin polymerization catalysis: Facing the challenges of miniaturization C Ehm, A Mingione, A Vittoria, F Zaccaria, R Cipullo, V Busico Industrial & Engineering Chemistry Research 59 (31), 13940-13947, 2020 | 27 | 2020 |
Chain transfer to solvent in propene polymerization with Ti Cp-phosphinimide catalysts: evidence for chain termination via Ti–C bond homolysis C Ehm, R Cipullo, M Passaro, F Zaccaria, PHM Budzelaar, V Busico ACS Catalysis 6 (11), 7989-7993, 2016 | 27 | 2016 |
Methylaluminoxane’s molecular cousin: A well-defined and “complete” al-activator for molecular olefin polymerization catalysts F Zaccaria, C Zuccaccia, R Cipullo, PHM Budzelaar, A Vittoria, ... ACS Catalysis 11 (8), 4464-4475, 2021 | 26 | 2021 |
BHT-Modified MAO: Cage Size Estimation, Chemical Counting of Strongly Acidic Al Sites, and Activation of a Ti-Phosphinimide Precatalyst F Zaccaria, C Zuccaccia, R Cipullo, PHM Budzelaar, A Macchioni, ... ACS Catalysis 9 (4), 2996-3010, 2019 | 25 | 2019 |
How a thermally unstable metal hydrido complex can yield high catalytic activity even at elevated temperatures C Ehm, J Krüger, D Lentz Chemistry–A European Journal 22 (27), 9305-9310, 2016 | 25 | 2016 |
Internal Donors in Ziegler–Natta Systems: is Reduction by AlR3 a Requirement for Donor Clean‐Up? F Zaccaria, A Vittoria, A Correa, C Ehm, PHM Budzelaar, V Busico, ... ChemCatChem 10 (5), 984-988, 2018 | 23 | 2018 |
Tuning the relative energies of propagation and chain termination barriers in polyolefin catalysis through electronic and steric effects C Ehm, PHM Budzelaar, V Busico European Journal of Inorganic Chemistry 2017 (27), 3343-3349, 2017 | 23 | 2017 |
A Systematic Study of the Temperature-Induced Performance Decline of ansa-Metallocenes for iPP C Ehm, A Vittoria, GP Goryunov, VV Izmer, DS Kononovich, PS Kulyabin, ... Macromolecules 53 (21), 9325-9336, 2020 | 22 | 2020 |