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Christian Ehm
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Role (s) of TMA in polymerization
C Ehm, R Cipullo, PHM Budzelaar, V Busico
Dalton Transactions 45 (16), 6847-6855, 2016
602016
Catalyst activation and the dimerization energy of alkylaluminium compounds
C Ehm, G Antinucci, PHM Budzelaar, V Busico
Journal of Organometallic Chemistry 772, 161-171, 2014
592014
Calculating accurate barriers for olefin insertion and related reactions
C Ehm, PHM Budzelaar, V Busico
Journal of Organometallic Chemistry 775, 39-49, 2015
522015
Accurate prediction of copolymerization statistics in molecular olefin polymerization catalysis: The role of entropic, electronic, and steric effects in catalyst comonomer affinity
F Zaccaria, C Ehm, PHM Budzelaar, V Busico
ACS Catalysis 7 (2), 1512-1519, 2017
452017
Backbone rearrangement during olefin capture as the rate limiting step in molecular olefin polymerization catalysis and its effect on comonomer affinity
F Zaccaria, R Cipullo, PHM Budzelaar, V Busico, C Ehm
Journal of Polymer Science Part A: Polymer Chemistry 55 (17), 2807-2814, 2017
352017
Selective copper complex-catalyzed hydrodefluorination of fluoroalkenes and allyl fluorides: a tale of two mechanisms
NO Andrella, N Xu, BM Gabidullin, C Ehm, RT Baker
Journal of the American Chemical Society 141 (29), 11506-11521, 2019
342019
Connection of Stereoselectivity, Regioselectivity, and Molecular Weight Capability in rac-R′2Si(2-Me-4-R-indenyl)2ZrCl2 Type Catalysts
C Ehm, A Vittoria, GP Goryunov, PS Kulyabin, PHM Budzelaar, ...
Macromolecules 51 (20), 8073-8083, 2018
322018
Chain transfer to solvent in propene polymerization with Ti Cp-phosphinimide catalysts: evidence for chain termination via Ti–C bond homolysis
C Ehm, R Cipullo, M Passaro, F Zaccaria, PHM Budzelaar, V Busico
ACS Catalysis 6 (11), 7989-7993, 2016
282016
How a thermally unstable metal hydrido complex can yield high catalytic activity even at elevated temperatures
C Ehm, J Krüger, D Lentz
Chemistry–A European Journal 22 (27), 9305-9310, 2016
242016
MgCl2-Supported Ziegler–Natta Catalysts: a DFT-D “Flexible-Cluster” Approach to Internal Donor Adducts
E Breuza, G Antinucci, PHM Budzelaar, V Busico, A Correa, C Ehm
The Journal of Physical Chemistry C 122 (16), 9046-9053, 2018
232018
Reactivity trends of lewis acidic sites in methylaluminoxane and some of its modifications
F Zaccaria, PHM Budzelaar, R Cipullo, C Zuccaccia, A Macchioni, ...
Inorganic chemistry 59 (8), 5751-5759, 2020
202020
Organocatalytic C− F Bond Activation with Alanes
AD Jaeger, C Ehm, D Lentz
Chemistry–A European Journal 24 (26), 6769-6777, 2018
202018
Metal–carbon bond strengths under polymerization conditions: 2, 1-insertion as a catalyst stress test
C Ehm, PHM Budzelaar, V Busico
Journal of Catalysis 351, 146-152, 2017
202017
An Integrated High Throughput Experimentation/Predictive QSAR Modeling Approach to ansa-Zirconocene Catalysts for Isotactic Polypropylene
C Ehm, A Vittoria, GP Goryunov, VV Izmer, DS Kononovich, ...
Polymers 12 (5), 1005, 2020
192020
BHT-Modified MAO: Cage Size Estimation, Chemical Counting of Strongly Acidic Al Sites, and Activation of a Ti-Phosphinimide Precatalyst
F Zaccaria, C Zuccaccia, R Cipullo, PHM Budzelaar, A Macchioni, ...
ACS Catalysis 9 (4), 2996-3010, 2019
192019
Internal Donors in Ziegler–Natta Systems: is Reduction by AlR3 a Requirement for Donor Clean‐Up?
F Zaccaria, A Vittoria, A Correa, C Ehm, PHM Budzelaar, V Busico, ...
ChemCatChem 10 (5), 984-988, 2018
192018
Catalyst mileage in olefin polymerization: the peculiar role of toluene
F Zaccaria, C Ehm, PHM Budzelaar, V Busico, R Cipullo
Organometallics 37 (17), 2872-2879, 2018
162018
Fluorinated butatrienes
C Ehm, FA Akkerman, D Lentz
Journal of Fluorine Chemistry 131 (11), 1173-1181, 2010
162010
Cyclic polyacetylene
Z Miao, SA Gonsales, C Ehm, F Mentink-Vigier, CR Bowers, BS Sumerlin, ...
Nature chemistry 13 (8), 792-799, 2021
152021
A Systematic Study of the Temperature-Induced Performance Decline of ansa-Metallocenes for iPP
C Ehm, A Vittoria, GP Goryunov, VV Izmer, DS Kononovich, PS Kulyabin, ...
Macromolecules 53 (21), 9325-9336, 2020
152020
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